I'm glad my computer doesn't blow up when I forget a semicolon, however some chemists don't have the same guarantee. So I'm glad I don't work with the stuff mentioned in the following link however reading about people that do is fascinating! So your turn:
pipeline.corante.com/archives/things_i_wont_work_with/
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And as for the first post on that page, about thioacetone smelling terrible, the worst I have come across in my lab is some sort of nutrient mix for bacteria - it's a horrible, somewhat-sulfur-y smell that is bloody awful.
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On the topic of incredibly dangerous chemicals that are actually used in labs I came across an article about this one a couple of months back:
http://en.wikipedia.org/wiki/Dimethylmercury
It's ability to go through latex gloves is quite scary...
Apparently it's used in calibrating MRI machines (or something like that).
It was linked from this hyperthetical:
http://www.schneier.com/blog/archives/2007/04/announcing_seco.html#c162272
which was a semifinalist in a competition to get ridiculous things banned by the TSA, the other entries are quite interesting too ( http://www.schneier.com/blog/archives/2007/06/second_annual_m.html ).
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