Just rewatching SV season 2. I've come across the unequivocal moment that could not possibly say it any louder to Clark that he and Chloe are meant to be.
It's in Visitor. When Clark and Chloe are having a discussion about Cyrus.
Clark says to Chloe 'You don't think he's really an alien do you?"
Chloe: *thinks about it a moment* ...No, but wouldn't
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