Does Timothy McGee from NCIS and myself count as a coupling? Haha! That geek is teh shex!

Erm, characters I've always wanted paired, would probably be... Inara and Mal (Firefly), McGee and Abby (NCIS), Zeva and DiNozzo (NCIS again), Hermione and Malfoy (Harry Potter) and Sara and Nick (CSI)