So I kind of made a supercut last night... I was watching The Boondock Saints again and lamenting my failure at quitting. I ended up going through the entire movie and clipping out every instance of smoking (cigarettes and cigars) I could see. Boston's "Smokin'" just happened to synch up with the rest of the video once I got my audio worked back in place. I managed to save it in HD thanks to the quality of the raw video file.
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I noticed one tiny clip that lasts about three quarters of a second and almost took it out-had a certain line in the song not synched up perfectly with another clip it would have been history.
Fixed. Incidentally, it's irritating that you can't replace video files that you've fixed. I had to delete the original.