This was so much harder than the track one, side ones. Honourable mentions go to Man Ray by The Futureheads (The Futureheads) and Down In The Tube Station At Midnight by The Jam (All Mod Cons). Anyways, here's the top 5. I encourage you to post your own, or at least reply with your own.
5. Gouge Away - The Pixies (Doolittle)
4. Train In Vain (Stand By Me) - The Clash (London Calling)
3. All Apologies - Nirvana (In Utero)
2. A Day In The Life - The Beatles (Sgt. Pepper's Lonely Hearts Club Band)
1. Sister Ray - The Velvet Underground (White Light/White Heat)
EDIT: Dear God removed, Train In Vain (Stand By Me) added.